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Best Management Practices

for

Nitrogen and Phosphorus Control

in

Further Processing Plants

October 11, 2001 Partial Draft, prepared by J. Willis Sneed of HDR, Inc.

I. Introduction

This document is intended to provide guidance for plant and corporate personnel in voluntarily establishing Best Management Practices (BMP) for to control nitrogen and phosphorus in the wastewater from red meat and poultry further processing plants. These nutrient control practices solely address in-plant waste minimization practices and do not include wastewater pretreatment or treatment methods.

This is one part of a three-part set of these documents. This part addressed BMP for cutting up the carcasses and further processing the meat. The other two documents discuss BMP for slaughter and rendering operations. Therefore it may be appropriate for some plants to use two or all three of these documents if they also slaughter or render.

II. Discussion of further processing plant types

In the mid-1970s, the U.S. Environmental Protection Agency (EPA) further processing plants into the following Subcategories:

Each of these categories is briefly described as follows:

These subcategories are not all-inclusive and many plants may not fit precisely into any of these categories. To characterize these plants it may be necessary to blend two or possibly more subcategories together.

III. Description of production-related activities

[pending]

IV. Typical nitrogen and phosphorus levels

In the mid-1970s, the Environmental Protection Agency (EPA) published Development Documents for both Red Meat Processing and Poultry. Included within both of those documents are tables showing waste characteristics for each subcategory within these industries. Table I shows data for total Kjeldahl nitrogen (TKN) from those Development Documents.

TABLE I
FURTHER PROCESSING PLANT EFFLUENT NITROGEN LEVELS

FROM 1970s DEVELOPMENT DOCUMENTS

Plant Type Average Range No. of Plants
  lb/1000 lb FP*   lb/1000 lb FP*    
Red Meat
Meat Cutter
  TKN

0.003

---- 1
  Ammonia-N 0.00078   ---- 1
  Nitrate-N 0.00053   ---- 1
  Nitrite-N 0.000024   ---- 1
Small Processor  
  TKN 0.667

0.133-1.2

2
  Ammonia-N 0.227

0.08-0.377

2
  Nitrate-N 0.0394  

0.024-0.055

2
  Nitrite-N 0.007  

0.0008-0.0133

2
Sausage and Luncheon Meats  
  TKN 0.256

0.0595-0.872

7
  Ammonia-N 0.0146

0.0013-0.034

7
  Nitrate-N 0.011

0.00017-0.032

5
  Nitrite-N 0.0029

0.00001-0.01

4
Ham Processor
  TKN

0.227

0.103-0.478

6
  Ammonia-N

0.016

0.01-0.032

6
  Nitrate-N

0.022

0.01-0.046

6
  Nitrite-N

0.0087

0.0001-0.03

7
Meat Canner  
  TKN

0.45

----

1
  Ammonia-N

0.074

----

1
  Nitrate-N

0.00045

----

1
  Nitrite-N

0.0016

----

1
Poultry Further Processing
  TKN 2.04  

----

1
  Ammonia-N

0.13

0.095-0.16

2

  Nitrate-N

0.018

----

1

  Nitrite-N

0.0019

----

1

* Finished Product

Table II shows effluent phosphorus levels for further processing plants.


TABLE II
FURTHER PROCESSING PLANT TOTAL PHOSPHORUS LEVELS
FROM 1970s DEVELOPMENT DOCUMENTS

Plant Type Average Range No. of Plants
 

lb/1000 lb FP*

lb/1000 lb FP*

 
Red Meat

Small Processor

0.227

0.133-0.33

2

Meat Cutter

0.005

----

1

Sausage and Luncheon Meats

0.175

0.0077-0.392

7
Ham Processor

0.288

0.01-0.08

7

Meat Canner

0.93

----

1

Poultry Further Processing

0.12

----

1

* Finished Product

All data in Table Nos. I-II represents plant effluents after physical pretreatment, i.e. no chemically-enhanced pretreatment. However pretreatment facilities were generally less extensive in the early 1970s than is presently typical.

V. Nitrogen and phosphorus sources


A. Nitrogen.

Total nitrogen is comprised of TKN, nitrate nitrogen and nitrite nitrogen. TKN is the combination of organic nitrogen and ammonia nitrogen. Table I shows that essentially all of the nitrogen in further processing plant effluents is in the form of TKN, with very little nitrate or nitrite nitrogen present. By far the major source of nitrogen is from the protein in the meat particles and blood in the wastewater from further processing plants. Protein contains about 16 percent organic nitrogen. Fat contains no nitrogen, nor is any contained in carbohydrates such as sugars, starches and cellulose. The primary source of carbohydrates in further processing plant wastewater is from curing and flavoring additives.

Since the general nitrogen contents in further processing plant effluents shown in Table I were determined in the early 1970s, tumbling or massaging of product has become common in further processing operations. This results in the release of protein from the product and discharge of these proteins in the wastewater. Unfortunately these salt-soluble proteins are not removed in wastewater pretreatment devices.

As protein is utilized by both aerobic and anaerobic saprophytic bacteria, organic nitrogen is broken down to ammonia. The longer the meat particles and blood are in contact with wastewater, the more the organic nitrogen will be converted to ammonia nitrogen. This is significant because organic nitrogen can be removed from the wastewater by physical pretreatment; such as fine screening, settling or flotation; but ammonia cannot because it is in solution. Although ammonia is often used in the refrigeration systems at further processing plants, it is not a significant source of nitrogen in the wastewater.

B. Phosphorus.

A significant source of phosphorus in further processing wastewater is also the proteins in the meat particles and blood. Lean meat contains approximately two percent [verify] organic phosphorus. Carbohydrates and fat contain small amounts of phosphorus. Pickle solutions, used to cure many meat products in further processing plants, contribute to phosphorus in packing plant wastewaters. If phosphate-bearing detergents are used for cleaning, these can be a source of phosphorus in the wastewater. Boiler-water additives only contribute minor amounts of phosphorus in the wastewater.

VI. Best management practices for nitrogen and phosphorus control

A. Pickle/Spice/Marinate Management: (Pickle is a solution of sugar, salt, lactates, phosphates, nitrites, etc. for bacon and ham curing. Marinate is a solution of sugar, salt, lactates, phosphates, nitrites, etc. for flavoring of poultry meat.)

  1. Use multiple smaller tanks, rather than fewer larger tanks to make up pickle solutions to minimize dumping large amounts of pickle or marinate when formulations change.
  2. Collect, screen and reuse spent pickle or marinate from the injection or tumbler machines.
  3. Bag product in plastic while horizontal to avoid runoff of pickle or marinate when product is hung vertically.

Impacts:

Comment: Physical pretreatment is ineffective in removing soluble pickle or marinate materials.

Impacts:

  1. Reduction in Total P, nitrite and BOD in the wastewater.
  2. Savings in pickle or marinate costs, which often costs over a dollar a gallon.

Comment: Physical pretreatment is ineffective in removing soluble pickle or marinate materials.

  1. Where possible, dry clean up ingredients spilled during make up of pickle or marinate.
  2. Repair or replace pump and valve seals as required to minimize or eliminate leaks of pickle or marinate.
  3. Strive to continuously eliminate pipe and equipment pickle/marinate leaks and spills.

Impacts:

  1. Reduction in Total P, nitrite and BOD in the wastewater.
  2. Savings in pickle or marinate costs, which often costs over a dollar a gallon.

Comment: Physical pretreatment is ineffective in removing soluble pickle or marinate materials.

B. Cleaning Chemical Management: Consider switching to low-phosphorus or non-phosphorus cleaning compounds. Phosphorous-based cleaners can often be replaced with organic surfactants (butyoxyethanol) and caustic cleaners (NaOH or KOH).

Impact: This step alone reduced phosphorus in the effluent from a pork low-processing packinghouse by approximately 2 mg/l for a six percent reduction.

Comments:

  1. Consider food safety concerns when evaluating a switch to a low-phosphorus or non-phosphorus product
  2. Low or non-phosphorus cleaning compounds may be less effective and more costly.
  3. Caustic cleaners can harm aluminum and copper equipment.

C. Solids Removal: Evaluate improvements to screening practices to physically remove solids from wastewater.

Impacts:

  1. Reduction of TKN, total P, BOD, TSS, and fat, oil and grease (FOG) in the wastewater. Rapid removal of meat scraps and blood from the floors prevents the breakdown of organic nitrogen to the ammonia form, which cannot be removed through pretreatment.
  2. More recovery of inedible material for rendering.

Comments:

  1. Occasional plugging may force more frequent cleaning of the drains and baskets.
  2. Removal of the baskets or emptying them into the open drain must be prohibited for this to be effective.

Impacts:

  1. Reduction of TKN, total P, BOD, TSS and FOG in the wastewater. Rapid removal of meat scraps and blood from the floors prevents the breakdown of organic nitrogen to the ammonia form, which cannot be removed through pretreatment.
  2. More recovery of inedible material for rendering.

D. Dry Cleanup:

a. Review the design of equipment to avoid creating difficulties with dry cleanup. For example, try to minimize numerous legs on equipment that inhibit use of a squeegee or shovel for dry cleanup.
b. Assign workers during the production shift(s) to dry cleanup materials from the floors for rendering.
c. Provide tools for dry cleanup, such as squeegees, shovels, dump carts, vacuums, etc.
d. Consider establishing and enforcing written standard operating procedures for dry cleanup, either at the end of the production shift or at the start of the sanitation shift

Impact:

  1. Reduction of TKN, total P, BOD, TSS and FOG in the wastewater. Rapid removal of meat scraps and blood from the floors prevents the breakdown of organic nitrogen to the ammonia form, which cannot be removed through pretreatment.
  2. More recovery of inedible material for rendering.

E. Inedible Material Management: Minimize the use of water to sluice meat scraps to inedible rendering trucks. This water must be drained from the raw materials before the inedible material is hauled away. This leaches blood and other soluble materials out of the inedible material and sends them to the sewer. Alternatives to sluicing include screw and belt conveyors, ram-type and other solids-handling pumps, blow tanks and vacuum systems.

Impact:

  1. Reduction of TKN, total P, BOD, TSS and FOG in the wastewater.
  2. More recovery of inedible material for rendering.

F. Water Conservation: Although there is no readily-apparent reason why water conservation would result in nitrogen and phosphorus reductions, the Development Documents all contain graphs showing that plants with lower water use per 1000 lb RM also had lower waste loads. Obviously less water is used, however, if a scrap of meat is picked up during dry cleaning than if it is hosed to a floor drain during sanitation, for example. This may also simply be an indication that better-run plants use less water and discharge less wastes versus poorer-managed plants in general.

Impact: Reduced water requirements for sanitation.

  1. Monitoring water use on a day-to-day, month-to-month, and year-to-year basis can detect daily excursions, as well as long-term trends. Gradually increasing water use for an individual piece of equipment may indicate spray nozzle openings are slowly wearing larger. Significant water flow during idle shifts and weekends may indicate water leaks.
  2. Consider establishing baseline quantities and holding each department manager responsible for water usage for his department. Reward usage under budgeted amounts and condemn usage of excessive quantities.
  3. Encourage competition for water reductions between shifts and between different departments

Impact: Less water usage; hence less pollutant discharge.

Impact: Reduced water requirements for sanitation.

G. Product Loss Prevention: Consider establishing procedures to monitor wastewater pollutant loadings (TKN, total P, BOD, TSS, and FOG).

Impacts:

  1. Reduced loadings for wastewater treatment, hence reduced waste treatment costs.
  2. Problem areas are identified and corrected.
  3. Allows measurement of the impact of waste reduction projects within the plant.

H. Pollution Prevention Team: Investigate establishing teams to identify methods to reduce water usage and plant waste, set goals, and monitor progress.

Impacts:

  1. Reduced water usage and waste loads.
  2. Recognition for employee efforts.

I. Environmental Awards Program: Consider participating in an industry-sponsored awards program or establishing corporate sponsorship of awards to plants, departments or individuals for both water and waste reduction. Plants could compete for awards with winners recognized by the industry or company management with a trophy or plaque.

Impacts: One corporation attributed annual savings over a $1 million/year to these projects, plus energy reduction.

VII. BMP monitoring

[pending]

Appendix

[pending]

References

[pending]